Mercury Instruments - Header
Top of page
Bottom of page

Mercury Stack Gas Monitor

SM-3

 

Continious emission monitor (CEM) for mercury

Mercury Instruments
  • Approved by TÜV
    (published in GMBl Nr. 33/1999)
  • Detects elemental, ionic
    and bound mercury
  • True continuous measurement
    (no measuring cycle)
  • No wet-chemistry
    no use of reagents
  • Maintenance-free
    solid state catalyst
  • Range 1 - 45; 0 - 75; 0 - 500 µg/m³ Hg
    (others optional)
  • Corrosion protected
    rugged construction
  • Compact size, mobile operation possible

Applications

The SM-3 Mercury Stack Gas Monitor is used for continuous monitoring of mercury in stack gas. Bound forms of mercury like HgCl2, HgO, HgS and particulate mercury are detected as well as elemental mercury.

  • Municipal Waste Incinerators
  • Sewage Sludge Incinerators
  • Hazardous Waste Incinerators
  • Cement Production
  • Coal Fired Power Plants
  • Thermal Soil Resanitation Plants
  • Wood Combustors Using Recycled Wood
  • Metal Recycling Furnaces
SM-3 Installation
at stack of a municipal waste incinerator
(Bavaria, Germany)
Sewage sludge incinerator
(Stuttgart, Germany)
SM-3 Installation inside
protection cabinet
(cement kiln, Germany)
Cement plant
with installation
of SM-3 on top of baghouse

Operating principle

A sample gas stream is taken from the duct through a heated sampling system. The gas is drawn through a high-temperature particulate filter and subsequently enters the reduction unit. In this part of the analyzer a thermo-catalytic reduction of ionic and bound mercury is performed. Elemental mercury vapor is formed as a result of this transformation process. The gas is then dried in a maintenance-free peltier cooler and fed to the mercury detector where the mercury concentration is measured with the so called "cold vapor atomic absorption spectroscopy (CVAAS)" method. The high surface temperature of the gas entry filter guarantees that mercury is thermally completely desorbed from particles and thus also detected.

Mercury Instruments

Schematic flow diagram of SM-3 Mercury Stack Monitor

Design features

All surfaces coming into contact with the sample gas are heated to temperatures >180°C to prevent any adsorptional loss of mercury . The sample line is made of perfluoralkoxy (PFA), a material which shows extremely weak interaction with mercury vapor. Sampling and reduction are performed at temperatures far above the dew point. Therefore no condensate is formed before all mercury is in elemental state. This minimizes signal noise and avoids nonspecific peaks.

The SM-3 avoids to use any gold collector for mercury preconcentration thus giving a very fast response and providing results continuously and in real-time. Possible problems connected with "poisoning" of the gold surface are thus eliminated.

The straightforward analysis avoiding wet-chemical sample treatment and avoiding a gold trap ensures high reliability and low maintenance.

To prevent the instrument from being plugged up by dust-particles, the SM-3 has a self-cleaning filter system which is operated by compressed air. The cleaning function is automatically activated every hour and is a matter of seconds

Easy to operate

The SM-3 is operated via a waterproof membrane keypad. All inputs required are selected in a readily understandable menu shown on the graphical display. It is also possible to initiate functions like zero adjustment and calibration check from an external computer.

Low maintenance and low costs of ownership

Thanks to the new thermo-catalytic sample treatment method no reagents are required. Compared to first generation instruments employing wet chemical sample preparation methods, the SM-3 features clearly increased reliability and requires only minimum maintenance. This results in particularly low cost of ownership and maximum availability.

Sampling system

The sample gas is extracted with a stainless steel probe and conducted through a heated tube to the analyzer. The entire sample line is made of perfluoralkoxy (PFA), a material guaranteeing a minimial memory effect. The dimensions of the sampling system mounting flange are customized (for example DN 80/PN 6 or ANSI 3"/ 150 lbs).

The importance of continuous mercury emission monitoring

Monitoring of mercury emissions from stack has become a global issue. More strict regulations by authorities as well as the public claim for a complete surveillance of incinerators have caused an increasing interest in continuous emission monitors (CEMs) for mercury. For the potential user of such systems it is important to find a reliable and economic solution. First generation CEMs for mercury were based on the automation of known laboratory methods. This resulted in high maintenance costs, unreliable operation, oversized and heavy construction and last but not least a high price.

Mercury Stack Gas Monitor SM-3: Technical Specifications

Measuring component: total mercury Hg (tot)
Measuring principle: thermocatalytic reduction, atomic absorption at 253.7 nm
Measuring range: 0 - 50 µg/m3
0 - 75 µg/m3
0 - 500 µg/m3
Detection limit: < 1 µg/m3
Response time T90: < 60 seconds
Measurement cycle time: none, continuous measurement without time gaps
Air supply: oil-less compressed air, approx. 1.5 bar (approx. 22 psi)
Operating temperature: 5 - 40 °C
Power supply: 230 VAC / 50 Hz (+10% / -15%)
Electrical power consumption: max. 1000 VA (analyzer)
max. 150 VA/m (sample line)
Signal outputs: 4-20 mA (max. load 500 Ohms)
digital status outputs (relais contacts)
Dimensions: 550 x 1000 x 700 mm (WxHxD)
Weight: approx. 50 kg
Approval: Test conducted by German TÜV (Munich),
Report Nr. 24020562/August 1999), published in GMBl 1999/Nr. 33.
Mercury Instruments As a leading supplier of high precision analytical equipment, we strive at all times to offer top quality solutions. Our products are manufactured according to the ISO 9001 quality regulations.

VM-3000

Download brochure: